HPVA II

The HPVA II Series of adsorption analyzers from Particulate Systems uses the static volumetric method to obtain high-pressure adsorption and desorption isotherms utilizing gases such as hydrogen, methane, and carbon dioxide. The volumetric technique consists of introducing [dosing] a known amount of gas [adsorptive] into the chamber containing the sample to be analyzed.

When the sample reaches equilibrium with the adsorbate gas, the final equilibrium pressure is recorded. These data are then used to calculate the quantity of gas adsorbed by the sample.

Description

This process is repeated at given pressure intervals until the maximum preselected pressure is reached. Then the pressure can be decreased to provide a desorption isotherm. Each of the resulting equilibrium points [volume adsorbed and equilibrium pressure] is plotted to provide an isotherm.

Excellent reproducibility and accuracy are obtained by using separate transducers for monitoring low and high pressures.

HPVA II Benefits

  • Dual free-space measurement for accurate isotherm data
  • Free space can be measured or entered
  • Correction for non-ideality of analysis gas using NIST REFPROP compressibility factors calculated from multiple equations of state
  • Reports provided as interactive spreadsheets
  • Isotherm and weight percentage plots created automatically
  • Tables of raw data used for report calculations
  • Real-time charts for Pressure vs. Time and Temperature vs. Time
  • Gas mixtures with up to three components can be used
  • Kinetic data provided for rate of adsorpotion calculations
  • Langmuir equation used to model Type I isotherms
  • High-precision, solid-state design high-pressure transducer provides a reading accuracy of ±0.04% full scale with a stablility of ±0.1%
  • Low-pressure pressure transducer provides a reading accuracy of ±0.15% of value
  • System can attain a maximum pressure of 200 bar
  • Hydrogen gas sensor automatically shuts down the system should a hydrogen leak occur
  • BET surface area, Langmuir surface area, and total pore volume calculations included

Specification

Physical
  • Height 88.9 cm (35 in.)
  • Width 50.8 cm (20 in.)
  • Depth 50.8 cm (20 in.)
  • Weight 27.2 kg (60 lbs.)
Electrical
  • Voltage 100 – 240 VAC.
  • Frequency 50 – 60 Hz.
Temperature
  • 10 to 45 °C (50 to 113 °F.)
  • 10 to 55 °C (14 to 131 °F.)

Documents

HPVA II

 

HPVA II Brochure

 

Application Note PS 04

 

Application Note PS 05

 

Application Note PS 06

 

Application Note PS 14